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Streszczenie:
This work describes an oxidation process of iron–iron oxide core–shell nanowires at temperatures between 100°C and 800°C. The studied nanomaterial was synthesized through a simple chemical reduction of iron trichloride in an external magnetic field under a constant flow of argon. The electron microscopy investigations allowed determining that the as-prepared nanowires were composed of self-assembled iron nanoparticles which were covered by a 3 nm thick oxide shell and separated from each other by a thin interface layer. Both these layers exhibited an amorphous or highly-disordered character which was traced by means of transmission electron microscopy and Mössbauer spectroscopy. The thermal oxidation was carried out under a constant flow of argon which contained the traces of oxygen. The first stage of process was related to slow transformations of amorphous Fe and amorphous iron oxides into crystalline phases and disappearance of interfaces between iron nanoparticles forming the studied nanomaterial (range: 25–300°C). After that, the crystalline iron core and iron oxide shell became oxidized and signals for different compositions of iron oxide sheath were observed (range: 300–800°C) using X-ray diffraction, Raman spectroscopy and Mössbauer spectroscopy. According to the thermal gravimetric analysis, the nanowires heated up to 800°C under argon atmosphere gained 37% of mass with respect to their initial weight. The structure of the studied nanomaterial oxidized at 800°C was mainly composed of α-Fe2O3 (∼93%). Moreover, iron nanowires treated above 600°C lost their wire-like shape due to their shrinkage and collapse caused by the void coalescence.

Słowa kluczowe:
annealing, core-shell nanostructure, iron nanoparticles, iron nanowires, oxidation, thermal treatment

Streszczenie:
The main goal of this work is to study the structural and magnetic properties of iron nanowires and iron nanoparticles, which have been fabricated in almost the same processes. The only difference in the synthesis is an application of an external magnetic field in order to form the iron nanowires. Both nanomaterials have been examined by means of transmission electron microscopy, energy dispersive X-ray spectrometry, X-ray diffractometry and Mössbauer spectrometry to determine their structures. Structural investigations confirm that obtained iron nanowires as well as nanoparticles reveal core–shell structures and they are composed of crystalline iron cores that are covered by amorphous or highly defected phases of iron and iron oxides. Magnetic properties have been measured using a vibrating sample magnetometer. The obtained values of coercivity, remanent magnetization, saturation magnetization as well as Curie temperature differ for both studied nanostructures. Higher values of magnetizations are observed for iron nanowires. At the same time, coercivity and Curie temperature are higher for iron nanoparticles.

Słowa kluczowe:
iron nanoparticles, iron nanostructures, iron nanowires, magnetic properties, structural properties

Streszczenie:
This work presents the results of high temperature annealing of iron nanowires at five different temperatures (ranging 200–800 °C) in the slightly oxidative atmosphere. Investigated nanomaterial was prepared in simple chemical reduction process from aqueous solution of iron trichloride placed in external magnetic field. Experimental results allowed determining how magnetic properties of as-prepared as well as annealed iron nanowires change in respect to their structures. They also delivered information about phase transitions occurred in as-prepared sample under thermal treatment.

Słowa kluczowe:
annealing, iron, magnetic properties, nanowires

Streszczenie:
The aim of this work is to study the preparation and characterization of a new nanocomposite which consists of chemically-modified multiwall carbon nanotubes covered by randomly-deposited nanoparticles of hematite. The morphology, structural and physical properties of the investigated nanomaterial were determined by means of transmission electron microscopy, X-ray diffraction and vibrating sample magnetometry at ambient conditions. The presence of residual catalyst nanospheres inside multiwall carbon nanotubes was confirmed by transmission electron microscopy. The signal coming from this contamination was under the detection limit of X-ray diffractometer, therefore it was not registered.

Słowa kluczowe:
Hematite, Multiwall carbon nanotubes, CVD, TEM, XRD, VSM