Pracownicy

Streszczenie:
At present, the problem of identifying and controlling different types of Mechanically
Separated Meat (MSM) is a very important practical issue in the meat industry. To address this
challenge, the authors propose a new, analytical method for the discrimination and characterization
of MSM that uses density measurements. The method proposed by the authors, in contrast to the analytical methods existing so far, is rapid, non-destructive, relatively simple and can be computerized.
The density measurements of meat samples were conducted with a modified pycnometric method.
Statistically significant (p < 0.01) differences were found in the evaluated mean values of density
for all investigated types of meat. Subsequently, the density measurements were correlated with
the physicochemical properties of meat samples. A high correlation coefficient was found between
the density of meat samples and the content of protein, sodium and fat. The authors have proven
that density measurements allow for rapid discrimination of various types of MSM, and can also be
effectively used to determine the chemical composition of MSM samples, e.g., the content of protein,
fat and sodium.

Słowa kluczowe:
Meat density; Mechanically Separated Meat (MSM); protein content; fat content; Sodium (Na) content; Calcium content (Ca)

Streszczenie:
An innovative analytical ultrasonic method for identification and investigation of Mechanically Separated Meat (MSM) samples is presented. To this end, the ultrasonic wave velocity (f = 5 MHz) in the investigated meat samples was measured. The measured ultrasonic velocity ranged from 1553.4 to 1589.9 m/s. The investigations were performed for: 1) minced hand deboned chicken fillets, 2) low pressure MSM from chicken carcasses, 3) low pressure MSM from chicken collarbones, 4) high pressure MSM from chicken carcasses and 5) high pressure MSM from chicken collarbones. Statistically significant (p < 0.001) differences in the ultrasonic velocity were observed for each of investigated kinds of meat. High significant correlations were found between the ultrasonic velocity and the content of protein, fat, sodium and density of the investigated meat. The applicability of the developed ultrasonic method for identifying various kinds of meat and to determine the content of protein, fat, sodium and density was demonstrated.

Słowa kluczowe:
physicochemical parameters, mechanically separated meat, ultrasonic velocity, protein content, calcium content, fat content

Streszczenie:
Vapors of benzene and its derivatives are harmful and toxic for human beings and natural environment. Their detection has fundamental importance. For this purpose authors propose surface acoustic wave (SAW) sensor with skeletonized layer deposited by Langmuir-Blodgett (L-B) method. This layer was obtained by depositing a binary equimolar mixture of 5-[[1,3-dioxo-3-[4-(1-oxooctadecyl) phenyl]propyl]amino]–1,3–benzenedicarboxylic acid with cetylamine. The skeletonized sensor layer has been obtained by removing cetylamine. Response of this sensor depends mainly of the electrical dipole momentum of molecule. Among the tested compounds, benzene has a zero dipole moment and gives the smallest sensor response, and nitrobenzene has the largest dipole moment and the sensor reacts most strongly to its vapor.

Słowa kluczowe:
SAW sensor, Langmuir-Blodget layer, vapors, benzene, benzene derivatives

Streszczenie:
In this work we analyse basic characteristics of Love wave sensors implemented in waveguide structures composed of a lossy viscoelastic surface layer deposited on a lossless elastic substrate. It has to be noted that Love wave sensors working at ultrasonic frequencies have the highest mass density sensitivity S among all known ultrasonic sensors, such as QCM, Lamb wave or Rayleigh wave sensors. In this paper we have established an exact analytical formula for the mass density sensitivity S of the Love wave sensors in the form of an explicit algebraic expression. Subsequently, using this developed analytical formula, we compared theoretically the mass density sensitivity S for various Love wave waveguide structures, such as: (1) lossy PMMA surface layer on lossless Quartz substrate and (2) lossy PMMA on lossless Diamond substrate. The performed analysis shows that the mass density sensitivity S (real and imaginary part) for a sensor with a structure PMMA on Diamond is five times higher than that of a PMMA on Quartz structure. It was found that the mass density sensitivity S for Love wave sensors increases with the increase of the ratio: bulk shear wave velocity in the substrate to bulk shear wave velocity in the surface layer.

Słowa kluczowe:
Love wave sensors, mass sensitivity, complex dispersion equation, viscoelastic layers

Streszczenie:
In this paper, the authors analyse the propagation of surface Love waves in an elastic layered waveguide (elastic guiding layer deposited on an elastic substrate) covered on its surface with a Newtonian liquid layer of finite thickness. By solving the equations of motion in the constituent regions (elastic substrate, elastic surface layer and Newtonian liquid) and imposing the appropriate boundary conditions, the authors established an analytical form of the complex dispersion equation for Love surface waves. Further, decomposition of the complex dispersion equation into its real and imaginary part, enabled for evaluation of the phase velocity and attenuation dispersion curves of the Love wave. Subsequently, the influence of the finite thickness of a Newtonian liquid on the dispersion curves was evaluated. Theoretical (numerical) analysis shows that when the thickness of the Newtonian liquid layer exceeds approximately four penetration depths 4δ of the wave in a Newtonian liquid, then this Newtonian liquid layer can be regarded as a semi-infinite half-space. The results obtained in this paper can be important in the design and optimization of ultrasonic Love wave sensors such as: biosensors, chemosensors and viscosity sensors. Love wave viscosity sensors can be used to assess the viscosity of various liquids, e.g. liquid polymers.

Słowa kluczowe:
Love waves, ultrasonic sensors, Newtonian liquid, penetration depth, biosensors, chemosensors, viscosity sensors

Streszczenie:
In this study, we analyze theoretically and numerically the properties of Love surface waves propagating in lossy multilayered composite waveguides, loaded on the upper surface with a Newtonian liquid. The propagation of Love surface waves was formulated in terms of a direct Sturm–Liouville problem. An analytical form of the complex dispersion equation of the Love surface wave was derived using the Thomson–Haskell transfer matrix method. By separating the complex dispersion equation into its real and imaginary parts, we obtained a set of two nonlinear algebraic equations, which were subsequently solved numerically. The effect of various physical parameters of the lossy viscoelastic waveguide on the velocity and attenuation of the Love surface wave was then analyzed numerically. It was found that because of the presence of losses in the analyzed waveguide, Love surface waves displayed a number of new original phenomena, such as resonant-like maxima in attenuation as a function of thicknesses h1 of the first viscoelastic surface layer and thickness h2 of the second elastic surface layer. These phenomena are completely absent in lossless waveguides.

Słowa kluczowe:
lossy waveguides, nondestructive testing of polymeric layered structures, Love surface waves, viscoelastic materials

Streszczenie:
An emerging ultrasonic technology aims to control high-pressure industrial processes that use liquids at pressures up to 800 MPa. To control these processes it is necessary to know precisely physicochemical properties of the processed liquid (e.g., Camelina sativa oil) in the high-pressure range. In recent years, Camelina sativa oil gained a significant interest in food and biofuel industries. Unfortunately, only a very few data characterizing the high-pressure behavior of Camelina sativa oil is available. The aim of this paper is to investigate high pressure physicochemical properties of liquids on the example of Camelina sativa oil, using efficient ultrasonic techniques, i.e., speed of sound measurements supported by parallel measurements of density. It is worth noting that conventional low-pressure methods of measuring physicochemical properties of liquids fail at high pressures. The time of flight (TOF) between the two selected ultrasonic impulses was evaluated with a cross-correlation method. TOF measurements enabled for determination of the speed of sound with very high precision (of the order of picoseconds). Ultrasonic velocity and density measurements were performed for pressures 0.1–660 MPa, and temperatures 3–30 °C. Isotherms of acoustic impedance Za, surface tension σ and thermal conductivity k were subsequently evaluated. These physicochemical parameters of Camelina sativa oil are mainly influenced by changes in the pressure p, i.e., they increase about two times when the pressure increases from atmospheric pressure (0.1 MPa) to 660 MPa at 30 °C. The results obtained in this study are novel and can be applied in food,and chemical industries.

Słowa kluczowe:
ultrasonic methods, speed of sound, acoustic impedance, surface tension, thermal conductivity, physicochemical properties

Streszczenie:
Modeling of high-pressure technological processes in the food industry requires knowledge of thermophysical parameters of processed foodstuffs in a broad range of pressures and temperatures. However, the high-pressure thermophysical parameters of foodstuffs are very rarely published in the literature. Therefore, further research is necessary to achieve a deeper insight into the biophysical and thermophysical phenomena under pressure to provide better control of technological processes and optimize the effects of pressure. The essential goal of this work is to evaluate the impact of high pressure and temperature on the thermophysical parameters of liquid foodstuffs on the example of diacylglycerol (DAG) oil (which attracted recently a considerable attention from research and industrial communities due to its remarkable benefits for health), using ultrasonic wave velocity and density measurements. Isotherms of adiabatic and isothermal compressibility, isobaric thermal expansion coefficient, internal pressure, and thermal pressure coefficient versus pressure were evaluated, based on the measurement of the compressional ultrasonic wave velocity and density of DAG oil at high pressures (up to 500 MPa) and at various temperatures. The adiabatic compressibility is affected mostly by the changes of pressure, i.e., it grows about four times when the pressure increases from the atmospheric pressure (0.1 MPa) to 400 MPa at a temperature of 50 °C. By contrast, the internal pressure is a pronounced function of the temperature, i.e., it increases six times when the temperature rises from 20 to 50 °C at a pressure of a 200 MPa. To perform numerical calculations, it was convenient to introduce a Tammann–Tait type equation of state to approximate the measured density isotherms of the investigated DAG oil. The results obtained in this paper can be applied in modeling and optimization of high-pressure technological processes and processing of foodstuffs. Evaluation of high-pressure isotherms of the considered thermophysical parameters of the DAG oil is an original authors' contribution to the state-of-the-art.

Słowa kluczowe:
high-pressure food processing, diacylglycerols, thermophysical parameters, isothermal compressibility, isobaric thermal expansion coefficient, ultrasonic methods

Streszczenie:
Investigation of the high-pressure thermophysical properties of biofuels, e.g., bulk modulus, Surface tension, and viscosity is of paramount importance in fuel injection systems in diesel engines. Another crucial and dangerous phenomenon that may occur in biofuels at high pressures is phase transition (solidification), which can drastically increase the viscosity of the biofuel. This effect may hamper proper operation of the engine, especially under cold-start conditions. Unfortunately, the availability of highpressure thermophysical properties of biofuels is still limited. The goal of this paper is to investigate the impact of high pressures on thermophysical properties of biofuels on the example of rapeseed fatty acid methyl esters (RME) in a wide range of pressures (0:1 to 250 MPa) and temperatures (5 to 20 _C). To this end we employed innovative ultrasonic techniques, i.e., the Bleustein-Gulyaev surface acoustic waves for measuring RME viscosity, and ultrasonic bulk compressional waves for measuring sound velocity in RME and consequently evaluating RME thermophysical parameters, e.g., bulk modulus and surface tension. The viscosity of the measured RME displayed an abrupt increase at pressures: 260 MPa (t Ľ 20 _C), 230 MPa (t Ľ 15 _C), 190 MPa (t Ľ 10 _C), and 130 MPa (t Ľ 5 _C). Evidently it was a signature of the phase transition (solidification) occurring in the RME. The discovered high viscosity high-pressure phase in RME can be very detrimental for operation of modern common rail Diesel engines. Therefore, the results of research presented in this paper should be interesting for engineers and designers working with modern common rail Diesel engines using biofuels.

Słowa kluczowe:
Biofuels, Methyl esters, Phase transitions, Viscosity, Speed of sound, Ultrasonic methods, High pressure

Streszczenie:
This paper presents a theoretical study of the propagation behavior of ultrasonic Love waves in nonhomogeneous functionally graded elastic materials, which is a vital problem in the mechanics of solids. The elastic properties (shear modulus) of a semi-infinite elastic half-space vary monotonically with the depth (distance from the surface of the material). The Direct Sturm–Liouville Problem that describes the propagation of Love waves in nonhomogeneous elastic functionally graded materials is formulated and solved by using two methods: i.e., (1) Finite Difference Method, and (2) Haskell-Thompson Transfer Matrix Method.

The dispersion curves of phase and group velocity of surface Love waves in inhomogeneous elastic graded materials are evaluated. The integral formula for the group velocity of Love waves in nonhomogeneous elastic graded materials has been established. The effect of elastic non-homogeneities on the dispersion curves of Love waves is discussed. Two Love wave waveguide structures are analyzed: (1) a nonhomogeneous elastic surface layer deposited on a homogeneous elastic substrate, and (2) a semi-infinite nonhomogeneous elastic half-space. Obtained in this work, the phase and group velocity dispersion curves of Love waves propagating in the considered nonhomogeneous elastic waveguides have not previously been reported in the scientific literature. The results of this paper may give a deeper insight into the nature of Love waves propagation in elastic nonhomogeneous functionally graded materials, and can provide theoretical guidance for the design and optimization of Love wave based devices.

Słowa kluczowe:
Ultrasonic Love waves, Functionally graded materials, Profiles of elastic constants, Direct Sturm–Liouville Problem, Group velocity

Streszczenie:
This paper presents the use of SH (Shear Horizontal) surface Love waves to determine the distributions of elastic parameters in nonhomogeneous Functionally Graded Materials. The advantage of Love waves applied to investigate the elastic properties of materials is that the Love wave energy (in contrast to the other types of waves, e.g., plate Lamb waves) is concentrated in the vicinity of the surface layer. The penetration depth of the SH surface Love waves depends on the frequency. Therefore, Love waves are particularly suitable for investigating the profiles of the mechanical properties in nonhomogeneous Graded Materials. Direct Problem (Direct Sturm-Liouville Problem) that describes the propagation of Love waves in nonhomogeneous graded materials has been formulated and solved numerically by applying the Transfer Matrix Method. The Inverse Procedure (Inverse Sturm-Liouville Problem) for determining the distribution of elastic properties versus depth in the nonhomogeneous materials has been developed. Love wave dispersion curves in nonhomogeneous graded materials were evaluated numerically (synthetic data). Using the evaluated dispersion curves of Love waves and a developed Inverse Procedure the distributions of elastic shear coefficient as a function of depth (distance from the surface of the material into the bulk) in a heterogeneous surface layer deposited on a homogeneous substrate have been evaluated. Power type profiles (i.e., root square, linear and quadratic) of the shear elastic coefficient in the surface layer were considered. The results of this study can be useful in the investigation of elastic properties of Graded Materials in electronics as well as in geophysics and seismology.

Słowa kluczowe:
Love waves, Inverse Methods, Functionally Graded Materials, Elastic parameters, Sturm-Liouville Problem

Streszczenie:
In many technological processes (e.g., in the chemical, petrochemical, food, and plastics industries), liquids are subjected to high pressures and temperatures. Therefore, knowledge of their thermodynamic properties is essential for understanding, design, and control of the process technology. Direct evaluation of the thermodynamic parameters of liquids under high pressure, using conventional methods, is very difficult. Therefore, the application of these methods in industrial conditions, particularly in on-line control of the technological parameters of liquids, is practically impossible. Ultrasonic methods (e.g., sound speed measurements) are very suitable for this purpose because of their simplicity and accuracy. The sound velocity is closely related to numerous thermodynamic properties of liquids. The objective of this paper is to address the influence of temperature and pressure on the thermodynamic parameters of liquids, using the example of diacylglycerol (DAG) oil, employing ultrasonic methods. In this paper, we present ultrasonic velocity and density measurements (performed by the authors) in DAG oil over a range of pressures and temperatures. On the basis of experimental results (the sound velocity and liquid density versus pressure and temperature) a series of DAG oil thermodynamic parameters such as specific heat ratio, intermolecular free path length, Van der Waals constant b, surface tension, and effective Debye temperature were evaluated as functions of pressure and temperature.

Słowa kluczowe:
Thermodynamical properties of liquid, High pressure food processing, ultrasonic methods, sound velocity, surface tension

Streszczenie:
This paper presents a theoretical study of the propagation behaviour of surface Love waves in nonhomogeneous functionally graded elastic materials, which is a vital problem in acoustics. The elastic properties (shear modulus) of a semi-infinite elastic half-space vary monotonically with the depth (distance from the surface of the material). Two Love wave waveguide structures are analyzed: 1) a nonhomogeneous elastic surface layer deposited on a homogeneous elastic substrate, and 2) a semi-infinite nonhomogeneous elastic half-space. The Direct Sturm-Liouville Problem that describes the propagation of Love waves in nonhomogeneous elastic functionally graded materials is formulated and solved 1) analytically in the case of the step profile, exponential profile and 1cosh2 type profile, and 2) numerically in the case of the power type profiles (i.e. linear and quadratic), by using two numerical methods: i.e. a) Finite Difference Method, and b) Haskell-Thompson Transfer Matrix Method.

The dispersion curves of phase and group velocity of surface Love waves in inhomogeneous elastic graded materials are evaluated. The integral formula for the group velocity of Love waves in nonhomogeneous elastic graded materials has been established. The results obtained in this paper can give a deeper insight into the nature of Love waves propagation in elastic nonhomogeneous functionally graded materials.

Słowa kluczowe:
surface Love waves, group velocity, phase velocity, functionally graded materials, profiles of elastic constants, direct Sturm-Liouville problem

Streszczenie:
High-pressure processing is a powerful technology for food preservation. The knowledge of foods properties in the high-pressure range is important to develop and optimize such processes by means of mathematical modeling and simulation. Ultrasonic methods are rapid, non-invasive and can be used to characterize foods like edible oils (e.g., composition, purity, and quality assessment). In this paper, they were applied for the investigation of physicochemical properties of olive oil at high pressure at different temperatures. The sound wave velocity was measured by the pulse-transmission method and the corresponding oil density was additionally determined from the monitoring of sample volume change. Measurements were conducted in the pressure range up to 600 MPa, for temperatures from 20 to 50°C. Intermolecular free length, isothermal and adiabatic compressibility versus pressure were calculated using measured sound speed and density isotherms. Discontinuities in the measured isotherms of sound speed and density versus pressure indicate the presence of liquid-to-solid phase transitions. The kinetics of the liquid-to-solid phase transition was also investigated. The transformation times of olive oil augment with increasing temperature. This study can be broadened to other liquid foodstuffs to investigate the influence of temperature on their physicochemical properties at high pressure.

Słowa kluczowe:
Physicochemical properties, Intermolecular free length, Ultrasonic velocity, High-pressure food processing, Olive oils

Streszczenie:
The purpose of the paper is to address, using ultrasonic methods, the impact of temperature and pressure on the physicochemical properties of liquids on the example of diacylglycerol (DAG) oil. The paper presents measurements of sound velocity, density and volume of DAG oil sample in the pressure range from atmospheric pressure up to 0.6 GPa and at temperatures ranging from 20 to 50°C.

Sound speed measurements were performed in an ultrasonic setup with a DAG oil sample located in the high-pressure chamber. An ultrasonic method that uses cross-correlation method to determine the time-of-flight of the ultrasonic pulses through the liquid was employed to measure the sound velocity in DAG oil. This method is fast and reliable tool for measuring sound velocity. The DAG oil density at high pressure was determined from the monitoring of sample volume change. The adiabatic compressibility and isothermal compressibility have been calculated on the basis of experimental data. Discontinuities in isotherms of the sound speed versus pressure point to the existence of phase transitions in DAG oil. The ultrasonic method presented in this study can be applied to investigate the physicochemical parameters of other liquids not only edible oils.

Słowa kluczowe:
Ultrasonic methods, Sound velocity, Phase transitions, High pressure food processing, Physicochemical parameters

Streszczenie:
The nonlinearity parameter B/A is a measure of the nonlinearity of the equation of state for a fluid. The nonlinearity parameter B/A is a physical parameter often used in acoustics, from underwater acoustics to biology and medicine. It can provide information about structural properties of the medium, internal pressure and inter-molecular spacing. The thermodynamic method has been applied for determination of B/A parameter in diacylglycerol (DAG) oil as a function of pressure at various temperatures. Isotherms of the density and phase velocity of longitudinal ultrasonic wave as a function of pressure have been measured. Using the thermo- dynamic method along with measured isotherms of sound speed and density, the nonlinearity parameter B/A (for DAG oil) was evaluated as a function of pressure (up to 220 MPa) at various temperatures ranging from 20 to 50◦C.

Słowa kluczowe:
Nonlinearity parameter B/A, thermodynamic method, high pressure, longitudinal ultrasonic wave velocity

Streszczenie:
In this paper (inspired by a newly developed class of
materials, i.e., elastic metamaterials) we will show that torsional
surface elastic waves can propagate on the surface of a
metamaterial elastic rod embedded in a conventional elastic space.
In this work, we assume that the elastic compliance
 of a
metamaterial cylindrical rod varies with frequency  according
to Drude model. The proposed torsional ultrasonic surface waves
can be considered as an elastic analogue of Surface Plasmon
Polariton (SPP) electromagnetic waves propagating on the surface
of a metallic rod embedded in dielectric space. An analytical
expression for the dispersion equation the new torsional elastic
surface wave was developed. The newly discovered torsional
elastic surface wave inherits many of fascinating properties of
electromagnetic counterpart such as: strong subwavelength
concentration of the wave field in the vicinity of the cylindrical
surface, low phase and group velocity etc. Therefore, the proposed
new torsional ultrasonic surface waves can be used in: a) near-field
subwavelength acoustic imaging (superresolution), b)
amplification of the evanescent waves

Słowa kluczowe:
Torsional surface acoustic waves, Surface Plasmon Polaritons (SPP) electromagnetic waves, Dispersion equation, Phase velocity, Group velocity

Streszczenie:
In this work we analyze basic characteristics of Love wave sensors implemented in waveguide structures composed of a lossy viscoelastic surface layer deposited on a lossless elastic substrate. It has to be noted that Love wave sensors working at ultrasonic frequencies have the highest mass density sensitivity S_σ^(v_p ) among all known ultrasonic sensors, such as QCM, Lamb wave or Rayleigh wave sensors. In this paper we have established an exact analytical formula for the mass density sensitivity S_σ^(v_p ) of the Love wave sensors in the form of an explicit algebraic expression. Subsequently, using this developed analytical formula, we compared theoretically the mass density sensitivity S_σ^(v_p ) for various Love wave waveguide structures, such as: (1) lossy PMMA surface layer on lossless Quartz substrate and (2) lossy PMMA on lossless Diamond. The performed analysis shows that the mass density sensitivity S_σ^(v_p ) for a sensor with a structure PMMA on Diamond is four times higher than that of a PMMA on Quartz structure. It was found that the mass density sensitivity S_σ^(v_p ) for Love wave sensors increases with the increase of the ratio: bulk shear wave velocity in the substrate to bulk shear wave velocity in the surface layer.

Słowa kluczowe:
love waves, mass sensitivity, dispersion equation, viscoelastic layers

Streszczenie:
In many technological processes liquids are subjected to high pressures (up to 800 MPa), e.g., in high pressure preservation of liquid foodstuffs. Similarly, in modern fuel injection systems for diesel engines, biofuels are subjected to pressures up to 300 MPa. In such severe conditions, thermophysical properties of liquid change considerably. Conventional methods for measuring thermophysical properties of liquids completely fail at high pressure conditions. Hence, these methods are of no use in real industrial conditions, during on-line monitoring of industrial processes. Thus, there exist a strong demand for industrial grade measurements methods, which can be used to monitor on-line the actual parameters of liquids. A very promising solution is offered by ultrasonic techniques which are particularly suitable for measurements of thermophysical properties of liquids at high pressures. In addition, the ultrasonic methods (that use low-intensity ultrasonic waves) are totally non-destructive and can be fully automated in real time.

Słowa kluczowe:
ultrasonic methods, thermophysical properties, high pressure, acoustic impedance, thermal conductivity

Streszczenie:
Progress in materials science has led to development of new materials with improved functional characteristics. One of the new types of materials introduced into industrial practice are plastics and polymers. These materials exhibit rheological (viscoelastic) properties, which combine simultaneously the properties of liquids and solids. Due to their attractive features, such as low specific weight, high resistance to chemical agents, ease of processing, cost ffectiveness etc. these materials are widely used in chemical, automotive, aviation and space industry. In addition, these materials are very common in many aspects of everyday life. Thus, it is very important, both from the theoretical and practical point of view, to develop new, robust and accurate methods to measure the rheological parameters (viscosity η, elasticity μ and density ρ) of plastics and polymers. The conventional mechanical methods used so far to this end are outdated, time consuming, and cumbersome. Ultrasonic methods do not possess these disadvantages. The first step in the formulation of the Inverse Method for evaluating the rheological parameters of viscoelastic liquids is to formulate and solve the Direct Sturm-Liouville Problem for Love waves propagating in the investigated layered elastic aveguide loaded on its surface with various types of viscoelastic materials (e.g., liquids). The aim of this study is to develop a rigorous mathematical model (Direct Sturm-Liouville Problem) of propagation of shear horizontal (SH) surface Love waves in layered viscoelastic structures, i.e., in layered elastic waveguides with a guiding surface layer covered with a viscoelastic material described by Kelvin-Voigt, Newton and Maxwell viscoelastic models respectively

Słowa kluczowe:
Love waves, viscoelastic liquid, Sturm-Liouville problem, dispersion curves

Streszczenie:
In many industrial technological processes, liquids are subjected to high pressures, e.g., in the high pressure food preservation. Similarly, in modern fuel injection systems for diesel engines, biofuel is subjected to a pressure up to 300 MPa. In such conditions, in liquids, high-pressure phase transitions (solidification) can occur that substantially increase the density and liquid viscosity. This solidification can result in significant problems with engine failure under cold-start conditions. This is an evident recipe for disaster, since the engine and its accessories would be very likely quickly destroyed. Thus, it is important to determine at what pressures and temperatures phase transitions occur. Conventional mechanical methods for measuring physicochemical properties of liquids at these extreme conditions do not operate. By contrast, ultrasonic techniques are very suitable for measurements of hysicochemical properties of liquids at high pressure, since they are non-destructive, can be fully automated and are characterized by the absence of moving parts. The aim of this work is to study the high-pressure hysicochemical properties of liquids (exemplified by a Camelina sativa - false flax oil) using novel ultrasonic methods.

Słowa kluczowe:
pressure, ultrasonic methods, phase transitions, Camelina sativa

Streszczenie:
The fundamental goal of this work is to verify the hypothesis of the existence of high-pressure phase transitions in biofuel components on the example of rapeseed fatty acid methyl esters (RME), by using ultrasonic methods. in a wide range of pressures (from atmospheric pressure to 300 MPa) and for various temperatures from 5 to 20 °C. Investigation of phase transitions in biofuels at high pressures is of great importance in the design of injection systems in modern diesel engines (common rail). Direct examination of phase transitions in liquids under high pressure, using classical methods, is very difficult. To overcome this disadvantage, the authors applied ultrasonic methods (viscosity measurement), which in contrast to the classical methods allow in a relatively simple way the investigation of high-pressure properties of liquids. Viscosity was measured by the original method that uses ultrasonic surface waves of the Bleustein-Gulyaev type, developed by the authors at the Institute of Fundamental Technological Research in Warsaw. From the measured viscosity isotherms, the occurrence of high-pressure phase transitions in methyl esters were evaluated.

Słowa kluczowe:
high-pressure phase transitions, biofuels, ultrasonic Bleustein-Gulyaev waves, viscosity measurements

Streszczenie:
Simultaneous determination of the rheological parameters of viscoelastic surface layers is very important in many applications such as: sensors, geophysics, seismology, and in the NDT of materials. Love wave energy is concentrated near the waveguide surface, so that Love waves are especially suited to study the material properties of surface layers. In this work, the Direct Sturm-Liouville Problem for the Love wave propagation in a layered viscoelastic waveguide have been presented and solved. Next, the Inverse Problem was created and solved as an Optimization Problem. The adequately formulated objective function that depends on the elastic and viscoelastic parameters of a waveguide of the Love wave and the experimental data was used. The solution of the Inverse Problem allows to determine unknown values of the viscosity and shear elasticity of a viscoelastic medium from measurements of the dispersion curves of Love waves.

Słowa kluczowe:
Love waves, rheological properties, viscoelastic materials, inverse problems, viscosity, shear elasticity

Streszczenie:
The aim of the study was to investigate the phase transitions in biofuel components by using ultrasonic methods on the example of methyl esters of fatty acids, in a wide range of pressures (from atmospheric pressure to 400 MPa) and for various temperatures from 5 to 20 °C. Investigation of phase transitions in biofuels at high pressures is of great importance in the design of injection systems in modern diesel engines (common rail). Direct examination of phase transitions in liquids under high pressure, using classical methods, is very difficult. To overcome this disadvantage, the authors applied ultrasonic methods (viscosity measurement), which in contrast to the classical methods allow in a relatively simple way the investigation high-pressure properties of liquids. Viscosity was measured by the original method that uses ultrasonic surface waves of the Bleustein-Gulyaev type, developed by the authors at the Institute of Fundamental Technological Research in Warsaw. From the measured viscosity isotherms, the occurrence and kinetics of high-pressure phase transitions in methyl esters were evaluated.

Słowa kluczowe:
High pressure phase transitions, physicochemical parameters of biofuels, ultrasonic viscosity measurements, rapeseed methyl esters

Streszczenie:
The aim of this study was to evaluate the inverse procedure to determine profiles (as a function of depth) of the mechanical properties of inhomogeneous FGM resulting from the application of various technological processes of surface treatment. First, the Direct Sturm-Liouville Problem for Love waves propagating in elastic graded materials with various profiles of the shear stiffness as a function of the distance from the surface, has been solved using the Finite Difference Method and Transfer Matrix Method (Haskell-Thompson method). Love wave dispersion curves were evaluated in the frequency range from 4 to 23 MHz. The Inverse Problem was formulated as an Optimization Problem with appropriately constructed objective function that depended on the material properties of an elastic waveguide of the Love wave and the experimental data. To minimize the considered objective function, optimization procedures of the Nelder-Mead type from Scilab software package were employed.

Słowa kluczowe:
Love waves, Inverse Methods, Functionally Graded Materials, Elastic parameters, Sturm-Liouville Problem

Streszczenie:
In many technological processes (e.g. in chemical, petrochemical, food and plastics industry) liquids are subjected to high pressures and temperatures. Therefore knowledge of their thermodynamic properties is essential for understanding, design and control of the process technology. Direct evaluation of thermodynamic parameters of liquids under high pressure, using conventional methods, is very difficult. Therefore, these methods are useless in industrial conditions, particularly in on-line control of the technological parameters of liquids. Ultrasonic methods (e.g., sound speed measurements) due to their simplicity and accuracy are very suitable for this purpose. The sound velocity is closely related with numerous thermodynamic properties of liquids. In this paper we report ultrasonic velocity and density measurements (performed by the authors) in diacylglycerol (DAG) oil over a range of pressures and temperatures. On the basis of experimental results (the sound velocity and liquid density versus pressure and temperature) the thermal expansion coefficient, specific heat capacity at constant pressure, isothermal and adiabatic compressibility of DAG oil were calculated as a function of pressure and temperature.

Słowa kluczowe:
Themodynamic parameters of liquids, high pressure, ultrasonic velocity, density, compressibility

Streszczenie:
The aim of this work was to establish an inversion procedure for the simultaneous determination of the viscosity and density of liquids. To this end, measurements of dispersion curves of the phase velocity and attenuation of shear horizontal Love waves were applied. Love waves propagate in an elastic layered waveguide covered on its surface with an investigated viscous (Newtonian) liquid. Firstly, the Direct Sturm-Liouville Problem of the Love wave propagation in a such waveguide was formulated and solved. Subsequently, the Inverse Problem was formulated and solved as an Optimization Problem. The appropriately constructed objective function that depends on the material properties of a waveguide of the Love wave, material properties of an investigated liquid (viscosity and density), and the experimental data was employed. The simultaneous determination of both liquid density and viscosity is important in the monitoring of technological processes in many industries (e.g. chemical, petroleum, pharmaceutical industry) as well as in geophysics.

Słowa kluczowe:
Love waves, Inverse Methods, Density, Viscosity of liquids, Sturm-Liouville Problem

Streszczenie:
High pressure research of the physicochemical properties of liquids has been stimulated by the fast development of such technologies as biodiesel production, high-pressure food processing and conservation, modification of biotechnological properties. Monitoring and studying liquid viscosity and ultrasonic wave velocity in liquids as a function of pressure and temperature enable to evaluate many important physicochemical parameters of liquids. These methods allow also insight into the phenomena governing the microstructural modifications occurring in treated substances, i.e. phase transitions. The knowledge of physicochemical properties (e.g. density, relaxation time, internal pressure or free volume) of pressurized substances is essential for understanding, design and control of the process technology. Measurements were conducted on the example of diacylglycerol oil (DAG oil), that is an important constituent of oils and fats.

Słowa kluczowe:
Physicochemical parameters of liquids, high pressure, ultrasonic velocity, viscosity of liquids, DAG oil

Streszczenie:
The nonlinearity parameter B/A is a measure of the nonlinearity of the equation of state for a fluid. It plays a significant role in acoustics, from underwater acoustics to biology and medicine. The nonlinearity parameter is important because it determines distortion of a finite amplitude wave propagating in the fluid. Moreover, it can be related to the molecular dynamics of the medium and it can to provide information about structural properties of medium, internal pressures, clustering, intermolecular spacing, etc. Importance of the B/A parameter increases with the development of high-pressure technologies. The thermodynamic method has been applied for determination of B/A parameter in diacylglycerol (DAG) oil as a function of pressure at various temperatures.

Słowa kluczowe:
Nonlinearity parameter B/A, Thermodynamic method, ultrasoniv velocity, high pressure

Streszczenie:
Podstawowym celem tej pracy jest przedstawienie możliwości zastosowania fal ultradźwiękowych do badania właściwości produktów spożywczych. Omówione zostaną rodzaje fal ultradźwiękowych (podłużne oraz poprzeczne) oraz ich rozchodzenie się w ciekłych oraz stałych produktach spożywczych (tj. w olejach oraz produktach mięsnych). Przedstawione będą nowe niespotykane właściwości fal ultradźwiękowych, które rozchodzą się w ciałach stałych oraz cieczach.
Na podstawie zmierzonych izoterm prędkości stwierdzono występowanie wysokociśnieniowych przemian fazowych w olejach roślinnych. Wyznaczenie pod wysokim ciśnieniem (do 600 MPa) parametrów fizykochemicznych olei roślinnych (czyli np. modułu objętościowego oraz napięcia powierzchniowego) oraz wykrycie oraz zbadanie wysokociśnieniowych przemian fazowych w olejach roślinnych jest nowością.
Z drugiej strony, identyfikacja różnych rodzajów mięsa metodami ultradźwiękowymi (tj. stosując pomiary prędkości fal ultradźwiękowych) jest także nowością i pozwala w sposób relatywnie prosty identyfikować różne rodzaje mięsa, tj. mięso oddzielone ręcznie od mięsa otrzymanego mechanicznie (MOM) czyli MOM niskociśnieniowy oraz MOM wysokociśnieniowy od mięsa wykrawanego ręcznie.
Badania przeprowadzone zostały przy współpracy autorów z Instytutu Podstawowych Problemów Techniki PAN oraz Instytutu Biotechnologii Przemysłu Rolno Spożywczego w Warszawie.

Słowa kluczowe:
Podłużne fale ultradźwiękowe, Prędkosć fazowa, Prędkość grupowa, Produkty spożywcze

Streszczenie:
Background, Motivation and Objective
Your text explaining what has been done previously and why this work is of importance.
We are currently witnessing a fascinating development of the theory of surface and bulk acoustic waves. New extraordinary properties in the domain of acoustic waves appeared with the invention of new materials, e.g., metamaterials. The use of elastic metamaterials for the construction of ultrasonic waveguides has created a fertile ground for the discovery of a series of new ultrasonic waves. In this paper, the author applied metamaterials to develop new cylindrical liquid viscosity sensors.
Classical ultrasonic cylindrical liquid viscosity sensors are made of conventional elastic materials. These sensors are usually used to determine the viscosity of liquids in biosensors and chemosensors. However, sensors of this type are not free from disadvantages. Namely, the ultrasonic field of this classical torsional wave is distributed in a large volume of the waveguide, which results in a moderate mass sensitivity of the cylindrical sensor. Therefore, the need to solve this problem arose. The aim of the author's work was to overcome this drawbacks. To solve this problem, the author used the extraordinary properties of elastic metamaterials. The waveguide proposed by the author consists of a metamaterial core immersed in a three-dimensional (3D) elastic external medium (see figure below). The mechanical susceptibility of the metamaterial cylindrical core can take negative and positive values. In this work, the author presented the theory of a new torsional ultrasonic wave propagating in metamaterial cylindrical waveguide structures. The new discovered cylindrical surface waves have only one axial mechanical displacement component (see figure below). The key property of the newly discovered torsional ultrasonic waves is that their mechanical displacement is concentrated close to the surface of the cylinder, which greatly increases the mass sensitivity of the sensor.
Statement of Contribution/Methods
Description of equipment, methods used.
Using the equations of motion (written in a cylindrical coordinate system), constitutive equations and the appropriate boundary conditions on the cylinder surface, we developed analytical formulas for the dispersion relation of the wave, phase and group velocities and the distribution of the mechanical displacement of the torsional wave as a function of the radius r.
/Discussion
Presentation of the results obtained and discussion of the results.
Phase and group velocity dispersion curves and the distribution of the mechanical displacement of the new torsional waves as a function of the radius r was determined. A very high concentration of energy was found near the surface of the cylinder for r=a which results in a large mass sensitivity of the new torsional waves. These new ultrasonic torsional waves have several times higher mass sensitivity than the conventional torsional bulk waves. It is worth noting that there is an electromagnetic (optical) analogue of the new ultrasonic torsional wave. The coefficient of mass sensitivity S_σ^v was evaluated numerically for torsional surface waves propagating in cylindrical waveguides composed of a PMMA metamaterial core embedded in ST-Quartz surrounding space, in the frequency range from 10 KHz to 10 MHz. The radius of the inner PMMA core was 0.5 1.0 and 2.0 millimeters, respectively. Conse-quently, the result presented in this work can be employed in design and optimization of torsional wave biosensors.

Słowa kluczowe:
Torsional surface acoustic waves, Surface Plasmon Polaritons (SPP) electromagnetic waves, Dispersion equation, Phase velocity, Group velocity

Streszczenie:
Despite the fact that Love surface waves have been discovered initially in seismology, as the waves occurring in the wake of earthquakes, they found recently numerous application in a benign domain of biosensors and chemosensors, following the pioneering works of P. Kiełczyński et. al. (1987-1989). Regardless of the fact that Love waves have been discovered over one hundred years ago (1911), there are still many interesting, fundamental problems about Love waves theory, their connections to other wave motions, etc., which remain unsolved. In this work, we analyze theoretically the properties of Love surface waves propagating in waveguides consisting of two different surface layers (upper and lower) deposited on a semi-infinite substrate. The upper surface of the waveguide is additionally covered with a semi-infinite layer of a Newtonian liquid occupying the half-space. In fact, the configuration of the waveguide represents a typical structure of the Love wave sensor, working in a liquid environment. By varying the viscosity of the Newtonian liquid covering the upper surface the waveguide, the authors have discovered a number of new intriguing phenomena displaying abrupt changing in Love wave parameters. In particular, for some selected values of the liquid viscosity, e.g., for η=11.9 Pas we have observed: 1) a dramatic change in the Love wave attenuation (approximately 15 times) and 2) a drastic change in the distribution of the mechanical displacement as a function of depth, i.e., the distance from the upper waveguide surface. This is accompanied by a pronounced redistribution of the power flow of the Love wave, i.e., the maximum of the power flow switches from the upper surface layer to the lower surface layer. To best of our knowledge, the above phenomena have not yet been reported in the scientific literature. The obtained results can be crucial in the design of Love wave sensors, as well as in seismology.

Słowa kluczowe:
Love waves, viscoelastic liquids, layered waveguides, dispersion curves

Streszczenie:
Knowledge of high-pressure behavior of the processed liquids is necessary to control technological processes in many branches of industry (e.g., in chemical, pharmaceutical and food industries). However, data on high-pressure behavior of liquids are still incomplete. The aim of this study is to investigate the high-pressure behavior (i.e., thermopysical parameters and possible high-pressure phase transitions) of liquids (on the example of Camelina sativa oil), applying ultrasonic methods (i.e., sound velocity and parallel density measurements). Camelina sativa (false flax) oil has found application in many branches of industry as well as a raw material for biofuel production. Generally, conventional methods for measuring thermophysical properties of liquids fail at high pressures. The solution to the problem can be the use of ultrasonic methods. Ultrasonic measurements were performed at f = 5 MHz for pressures 0.1 - 660 MPa, and for temperatures 3 - 30 ºC. Pronounced high-pressure phase transitions were discovered by the authors in Camelina sativa oil. The use of ultrasonic methods has enabled the determination of many physicochemical parameters of Camelina sativa oil, such as: 1) adiabatic compressibility β_a, 2) thermal expansion coefficient α_p, 3) specific heat at constant pressure c_p, 4) thermal conductivity k and 5) thermal diffusivity a. The results obtained in this study are novel and can be employed to design and control technological processes in many branches of industry

Słowa kluczowe:
Ultrasonic methods, high pressure, thermophysical properties, Camelina sativa

Streszczenie:
The aim of this work was to evaluate the impact of temperature and high pressure on thermophysical properties of liquids, exemplified by a Camelina sativa (false flax) oil. Camelina sativa oil has gained recently a growing interest due to its health-promoting effect as well as for its potential use in biodiesel production. To achieve the above objective, we measured the speed of sound and density in the selected oil. The speed of sound is directly associated to many thermophysical parameters of liquids. Hence, measurements of ultrasonic longitudinal wave velocity (f = 5 MHz) and liquid density, as a function of pressure and temperature, allowed determination of several important thermophysical parameters of the investigated liquid. The speed of sound in the liquid was determined from the time of flight measured with the cross-correlation method. To perform numerical calculations, it was helpful to introduce a Tammann–Tait type equation of state to approximate the measured density isotherms of the investigated Camelina sativa oil.

Słowa kluczowe:
Speed of sound, high pressure, cross-correlation method, thermophysical parameters, Camelina sativa oil

Streszczenie:
It is very important from a practical point of view, to develop new and accurate methods of measuring the rheological parameters (viscosity η, elasticity μ and density ρ) of plastics and polymers. New materials require new methods of measuring their rheological parameters. To evaluate the rheological parameters of plastics so far mechanical methods are used. These methods are cumbersome, outdated and destructive. The use of SH (Shear Horizontal) surface Love waves, to evaluate rheological parameters of polymers, does not possess these disadvantages. The objective of this work is to establish a mathematical model of propagation of Love waves in layered elastic waveguides covered on their surface with viscoelastic materials described by different viscoelastic models, i.e., Kelvin-Voigt, Newton and Maxwell models. To this end, we developed a complex dispersion equation for Love waves propagating in loaded waveguides and performed numerical calculations.

Słowa kluczowe:
Viscoelasticity, Love waves, Kelvin-Voigt model, Maxwell model, Complex dispersion equation

Streszczenie:
Background, Motivation and Objective: In many industrial technological processes, liquids are subjected to high pressures, e.g., in the high pressure food preservation. Similarly, in modern fuel injection systems for diesel engines, biofuel is subjected to a pressure up to 300 MPa. In such conditions, in liquids, phase transitions can occur that substantially increase the density and liquid viscosity. This can be very detrimental for the engine or the technological equipment. Thus, it is important to determine at what pressures and temperatures phase transitions occur. Conventional mechanical methods for measuring physicochemical properties of liquids at these extreme conditions do not operate. By contrast, ultrasonic techniques are very suitable for measurements of physicochemical properties of liquids at high pressure, since they are non-destructive and can be fully automated. The aim of this work is to study the high-pressure physicochemical properties of liquids (exemplified by a camelina sativa - false flax oil) using novel ultrasonic methods.

Słowa kluczowe:
High pressure, Biofuels, Viscosity, Phase transitions

Streszczenie:
Progress in materials engineering has led to development of new materials with improved functional characteristics. One of the new types of materials introduced into industrial practice are plastics and polymers. These materials exhibit rheological (viscoelastic) properties, which combine simultaneously the properties of liquids and solids. Due to their attractive features, such as low specific weight, high resistance to chemical agents, cost effectiveness etc. these materials are widely used in chemical, automotive, aviation and space industry. Thus, it is very important to develop new, robust and accurate methods to measure the rheological parameters (viscosity η, elasticity μ and density ρ) of plastics and polymers. The conventional mechanical methods used so far to this end are outdated, time consuming, and cumbersome. To overcome this problems, the authors propose the use of ultrasonic methods that employ surface Love waves, what is a novelty.

Słowa kluczowe:
Love waves, Rheological parameters, Rheological models, Polymers